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991.
The coagulation phase separation of solutions of novel copoly(phthalazinone amide)s is studied by the cloudpoint titration method. The effects of some factors on the coagulation value (V 1) and critical concentration (C c ) are investigated. It is shown that water is a strong coagulant, having a low coagulation value V 1 and that the V 1 increases with the increase of coagulant concentration and temperature. In addition, an increased percentage of LiCl in the coagulant and of phthalazinone moiety in the polymer main chain can slow down the phase separation speed. 相似文献
992.
The complex dielectric constant of natural rubber samples cross-linked by sulfur and dicumyl peroxide has been measured over a frequency range from 1.5 to 3.0 × 105 cps by the bridge method and from 3.0 to 1.0 × 104 cps by the relaxation method. Two dispersion peaks were detected which lay in the measured frequency range at temperatures above the main dispersion zone. Temperature and cross-link density-dependent shift of these peaks were studied and compared with the results obtained by Ferry et al. from complex compliance measurements performed on analogous systems. 相似文献
993.
《Journal of Macromolecular Science: Physics》2013,52(4-6):1331-1348
A propylene homopolymer and three copolymers with 1-decene containing 1.82, 3.55, and 7.83 mol% of comonomer units, respectively, were prepared with metallocene catalyst and the phase behavior in the melt of these polymers was studied using simultaneous synchrotron small-angle x-ray scattering and differential scanning calorimetry. The results show that the phase behavior of the melt varies with comonomer content and the copolymers tend to be phase-separated with increasing comonomer content. The phase separation in the melt of the propylene–1-decene copolymers was further confirmed by the fitting of the experimental data with Teubner–Strey micro-emulsion model and a transition from the phase-separated melt to the disordered melt was observed. We tentatively attribute this phenomenon to the inhomogeneous intra-molecular composition distribution at high levels of comonomer and the incompatibility of propylene sequences with different lengths. Such a finding is consistent with the facts of multiple melting peaks and mixed γ and α crystal phases in the polymer solids. Since the phase behavior depends on temperature, the effect of annealing temperature, from which the copolymers were cooled, on the nonisothermal crystallization of the copolymers was also investigated. It is found that higher degree of phase separation accelerates the crystallization but reduces the crystallization enthalpy. 相似文献
994.
《Journal of Macromolecular Science: Physics》2013,52(4-6):1023-1032
Real-time SAXS and WAXS patterns have been simultaneously obtained during isothermal melt-crystallization of blends of low-molecular-weight poly(ethylene oxide) (PEO) and poly(methyl methacrylate) (PMMA). The analysis of results shows that the originally homogeneous, single-phase polymer blend separates into two phases. The PMMA molecules diffuse from the blend and form completely segregated regions while PEO starts to crystallize. The first and dominating effect at the beginning of crystallization is the formation of unstable lamellae of nonintegrally folded chains (NIF). The real-time crystallinity and density of the PEO crystalline phase in absolute units were obtained from the time-resolved SAXS/WAXS results. The structure development proceeds in two steps. A very fast evolution of PEO crystals from the melt starts to crystallize in disordered NIF lamellae with thick amorphous interlayers and with a lower density of crystalline phase. The steep growth of crystallinity and crystalline density mean quick thickening of crystalline part of lamellae and improvement of their crystalline structure. In the second step, the structure of the crystalline phase gradually improves and crystallinity grows very slowly. The recrystallization of NIF lamellae into extended chain lamellae (EC) and lamellae with once folded chains (1F) proceeds during both stages of crystallization. 相似文献
995.
Biocompatible, highly interconnected microporous poly(L-lactic acid) (PLLA) foams with nanofibrous structure, containing pores with average diameter below 1 μm and fibers with diameters of 102 nm scale, were prepared through the thermally induced liquid–liquid phase separation (TIPS) method consisting of quenching of the PLLA solution, freeze extraction with ethanol, and vacuum drying. Diverse foam morphologies were obtained by systematically changing parameters involved in the TIPS process, such as polymer concentration, solvent composition, and quenching temperatures. The morphology of different foams was examined by scanning electron microscopy to characterize the pore size and the pore size distribution. The results showed that most porous foams had a nanofibrous structure with interconnected open pores. In the case of using tetrahydrofuran (THF) as solvent, the higher the PLLA concentration, the smaller the average pore diameter and the narrower the pore size distribution. In the case of using the mixed solvents of THF/DOX (1,4-dioxane) with higher than 6/4 volume ratio, there appeared a maximum value of average pore diameter and a widest pore size distribution at 0.09 g/mL PLLA concentration. The average pore diameter of the foams increased with increasing DOX content in the mixed solvent and ranged from 0.2 to 0.9 μm depending on the process parameters. When the DOX content reached 60% by volume, the morphology of the foams contained some large closed pores with diameter ranging from 1 to 10 μm. By decreasing the quenching temperature, the average pore diameter of foams decreased and the pore size distribution became narrower. All the pore size distribution fit F-distribution equations. 相似文献
996.
《Journal of Macromolecular Science: Physics》2013,52(2):459-470
Abstract Melting and crystallization behavior of poly(ethylene oxide) (PEO) with different molecular weight was investigated by modulated‐temperature differential scanning calorimetry (MT‐DSC)—step‐scan alternating DSC. It was found that by separating the reversing and nonreversing components of the (total) heat flow, PEO 10000, which exhibits the highest degree of crystallinity, shows the smallest nonreversing signal during crystallization. This effect can be attributed to the favorable structural features associated with spacial alignment. On the other hand, the crystallization process of PEO with molecular weight of 3400 is hindered by a relatively high content of end groups that may cause defects in the crystal lattice. For PEO 35000, low segmental mobility and chain entanglements lower the rate of crystallization. The area of the reversing component of PEO melting for different molecular weight fractions confirms that for PEO 10000, recrystallization is less intensive than for both the lower and higher molecular weight analogues. 相似文献
997.
Significant differences have been observed in the steady-state permeation of gases through symmetric and asymmetric (Loeb-type) cellulose acetate membranes. The studies were made with O2, N2, Ar, Kr, Xe, and CO2 in the temperature range from -5 to 85°C and at subatmospheric pressures. The differences in permeation behavior may reflect structural differences between the symmetric membranes and the dense surface layer (“skin”) of the asymmetric membranes. The overall mechanism of gas permeation through the symmetric membranes appears to be one of “solution-diffusion,” similar to that observed with many other nonporous polymeric membranes. In the case of the asymmetric membranes, this mechanism is probably modified by the presence of micropores or other imperfections in the dense surface layer. Cellulose acetate exhibits two second-order transitions in the presence of the penetrant gases, one between 60 and 70°C and the other near 15°C. The transitions were observed with both types of membranes. 相似文献
998.
We have used Ramakrishnan–Yussouff (RY) density functional theory (DFT) to explore the topology of the phase diagram of two-component charge stabilised colloidal suspensions confined to a two-dimensional plane. The particles of the system interact via purely repulsive soft core Yukawa potential. Pair correlation functions (PCFs) used as input informations in DFT were calculated by solving both the hypernetted chain (HNC) and Percus–Yevick (PY) integral equation theories. To test the relative performance of the HNC and PY theories in the context of phase transitions, we have also studied the corresponding one-component systems. We found that RY DFT with HNC PCFs does not stabilise solid in both the one- and two-component cases, whereas the PY theory does. By considering the freezing into the substitutionally disordered triangular solid, we found that the temperature-composition phase diagrams of the binary mixture are narrow spindles whose thickness depends on the symmetry of the mixture components and the value of the screening constant of the Yukawa potential. Although the phase diagram obtained by RY DFT with structural inputs calculated by the PY theory is found to be shifted to higher temperature region in the temperature-composition plane, however, it captures qualitatively all the essential features of the phase diagram. Our results are in principle verifiable through computer simulations and experiments. 相似文献
999.
1000.
We present a method for calibrating the position error of phase retrieval with transverse translation diversity in optical wavefront in situation where the position error sharply influences algorithm precision. This method involves testifying that the essence of the position error in phase retrieval is the translation in frequency domain and the minimum of iterative error against position error reaches when there is no position error. Then the least square method is used for fitting the relationship between the iterative error and the assumed position error in polynomial function. The computer simulations used to prove the validity of this method are described. The results indicated that this method can calibrate the position error to approximately 1/500 mm which nearly has no influence on the phase retrieval. 相似文献